Introduction
Antibacterial thin-film coatings have emerged as an important technological solution for improving hygiene and biosecurity in controlled agricultural environments such as commercial greenhouses. These environments are frequently exposed to both phytopathogens and human-associated bacteria that can persist on glass surfaces, tools, and structural components. Conventional cleaning methods are often insufficient for long-term microbial control, highlighting the need for durable, self-disinfecting surfaces. In this context, multifunctional antimicrobial glass coatings produced via advanced physical vapor deposition techniques represent a promising research direction, combining optical transparency, mechanical robustness, and sustained antibacterial activity.
Relevance of Greenhouse-Associated Pathogens
Greenhouse environments provide favorable conditions for microbial growth due to high humidity, stable temperatures, and frequent human interaction. Phytopathogens such as Pseudomonas syringae pose significant threats to crop productivity, while human pathogens including Escherichia coli, Micrococcus luteus, and Staphylococcus aureus raise concerns for occupational health and food safety. Research into surface-based antimicrobial strategies is therefore critical to reduce cross-contamination, limit disease spread, and support sustainable agricultural practices without excessive reliance on chemical disinfectants.
Magnetron Sputtering for Antibacterial Coating Fabrication
Magnetron sputtering is a highly versatile physical vapor deposition technique that enables precise control over thin-film composition, thickness, and uniformity. Its suitability for coating large-area substrates makes it particularly attractive for industrial-scale greenhouse glass applications. By employing multi-alloy targets, this method allows systematic tuning of elemental composition, facilitating the design of coatings with optimized antimicrobial performance while maintaining structural integrity and optical clarity.
Structural and Compositional Characterization of Thin Films
Advanced microscopy techniques, including high-resolution transmission electron microscopy, scanning transmission electron microscopy, and energy-dispersive X-ray spectroscopy, play a central role in understanding the microstructure and elemental distribution of sputtered coatings. Detailed characterization reveals nanoscale homogeneity, phase distribution, and alloying behavior, which are essential for correlating coating composition with antibacterial efficacy, mechanical durability, and corrosion resistance.
Antibacterial Performance of Cu-Based Multi-Alloy Coatings
Experimental evaluation against both Gram-negative and Gram-positive bacteria demonstrates that Cu-based coatings exhibit particularly strong antibacterial activity. Thin films derived from 90%Cu–10%Sn, 90%Cu–10%Zn, and 80%Cu–20%Ti targets showed some of the highest antimicrobial efficiencies across all tested strains. These findings support the hypothesis that copper, when combined with selected alloying elements, enhances bacterial inactivation through synergistic mechanisms while retaining coating stability.
Industrial Applicability and Future Research Directions
Beyond antimicrobial performance, the investigated coatings demonstrated excellent mechanical durability and corrosion resistance, both of which are critical for long-term greenhouse use. The ability to deposit uniform coatings on large glass panels underscores their industrial feasibility. Future research should focus on long-term field testing, optimization of alloy compositions for specific pathogens, and assessment of environmental safety, paving the way for next-generation antimicrobial greenhouse materials.
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